Abstract

The energy density of lithium-ion batteries based on intercalated electrode materials has reached its upper limit, which makes it difficult to meet the growing demand for high-energy storage systems. Electrode materials based on conversion reactions such as sulfur, organosulfides, and oxygen involving breakage and reformation of chemical bonds can provide higher specific capacity and energy density. In addition, they usually consist of abundant elements, making them renewable. Although they have the aforementioned benefits, they face numerous challenges for practical applications. For example, the cycled products of sulfur and molecular organosulfides could be soluble in liquid electrolyte, resulting in the shuttle effect and significant capacity loss. The discharged product of oxygen is Li₂O₂, which could result in high charge overpotential and decomposition of electrolyte. In this review, we present an overview of the recent strategies for improving the performances of lithium-sulfur, lithium-organosulfide, and lithium-oxygen batteries. First, we summarize the efforts to overcome the issues facing sulfur and organosulfide cathodes, as well as the strategies to increase the capacity of organosulfides. Then, we introduce the latest research progress on catalysts in lithium-oxygen batteries. Finally, we summarize and provide outlooks for the conversion electrode materials.