fig2

Modulating the lithiophilicity at electrode/electrolyte interface for high-energy Li-metal batteries

Figure 2. (A) Surface structure of Li metal in a 1,3-dioxolane (DOL), 1,2-dimethoxyethane (DME) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) ether-based electrolyte and an optimized hybrid electrolyte by using hybrid N-propyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)amide (Py13TFSI) and ether electrolyte in rechargeable Li-metal batteries[26]. Copyright 2016, Wiley-VCH. (B) Li3PO4-modified Li metal anode exhibiting a smooth and uniform surface after Li plating/stripping[32]. Copyright 2015, Wiley-VCH. (C) Different interfacial structural characteristics of bare Li metal and Li metal coated with polymer skin[35]. Copyright 2017, American Chemical Society. (D) Preparation process of polished Li foil in a naphthalene solution[44]. Copyright 2018, Elsevier. (E) AFM characterization showing the morphology of polished Li metal surfaces after plating in the electrolyte of 1 M lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in a mixture of dimethoxyethane/1,3-dioxolane (DME/DOL, v/v=1:1)[45]. Copyright 2018, Nature Publishing Group.

Energy Materials
ISSN 2770-5900 (Online)
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