fig5

Fundamentals and perspectives of electrolyte additives for non-aqueous Na-ion batteries

Figure 5. Influence of phosphorus-containing additives: (A) flammability and ionic conductivity of 1M NaPF6 + EC/DEC (1/1) electrolyte with different amounts of EFPN additive; (B) the 1st, 2nd, and 200th cycles of AB/Na half-cell with 1M NaPF6 + EC/DEC (1/1) + 5% vol. EFPN electrolyte; Reproduced from ref[61], Copyright 2015 RSC; (C) The cycling performances of Na3V2(PO4)2F3/C cells with various electrolytes at 55 °C; (D) the percentage of capacity retention and recovery after the self-discharge measurements of Na3V2(PO4)2F3/C cells at 100% state of charge for one week. Reproduced from ref[68], Copyright 2019 IOP Publishing Limited. DEC: Diethyl carbonate; DMC: dimethyl carbonate; EC: ethylene carbonate; EFPN: ethoxy(pentafluoro)cyclotriphosphazene; NaODFB: sodium (oxalate) difluoro borate; SET: self-extinguishing time; TMSPi: tris(trimethylsilyl) phosphite; VC: vinylene carbonate.

Energy Materials
ISSN 2770-5900 (Online)
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