fig4

Progress in the high-temperature synthesis of atomically dispersed metal on carbon and understanding of their formation mechanism

Figure 4. (A) Topological illustration of ZIF-67 and ZIF-8[72], reproduced from Ref.[72] with permission. Copyright 2010 American Chemical Society. (B) Illustration of the preparation of Mn-N-C via metal nods replacement and (C) HAADF-STEM image and EDS element mapping of Mn-N-C[73], reproduced from Ref.[73] with permission. Copyright 2020 American Chemical Society. (D) Illustration of the preparation of ADMCs via host-guest interaction[74], reproduced from Ref.[74] with permission. Copyright 2020 Springer Nature. (E) Pore diameter distribution of ZIF-8 and Co(acac)3@ZIF-8 and (F) Co K-edge XANES spectra of Co(acac)3@ZIF-8 and Co(mIm)4@ZIF-8[75], reproduced from Ref.[75] with permission. Copyright 2020 Springer Nature. (G) UV-vis spectra of the centrifuged supernatant after different washing steps and (H) Fe weight ratio in different Fc@ZIF-8 vs. the amount of Fc added during the fabrication process[76], reproduced from Ref.[76] with permission. Copyright 2018 Wiley-VCH. (I) Aberration-corrected HAADF-STEM images of Ru3@ZIF-8[77], reproduced from Ref.[77] with permission. Copyright 2019 Wiley-VCH. (J) Illustration of the preparation of defect-coupled FeN4 via host-guest interaction and (K) TEM and (L) aberration-corrected HAADF-STEM images of Fe SAs-N/C-20[78], reproduced from Ref.[78] with permission. Copyright 2018 American Chemical Society.

Energy Materials
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